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A solution is 40.00% by volume benzene (C6H6) in carbon tetrachloride at 20°C.The vapor pressure of pure benzene at this temperature is 74.61 mmHg and its density is 0.87865 g/cm3; the vapor pressure of pure carbon tetrachloride is 91.32 mmHg and its density is 1.5940 g/cm3.If this solution is ideal,its total vapor pressure at 20°C is


A) 84.64 mmHg.
B) 84.30 mmHg.
C) 82.96 mmHg.
D) 81.63 mmHg.
E) 165.93 mmHg.

F) D) and E)
G) A) and E)

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What mass of water is required to dissolve 27.8 g of ammonium nitrate NH4NO3 in order to prepare a 0.452 m solution?


A) 0.0615 kg
B) 0.100 kg
C) 0.177 kg
D) 0.768 kg
E) 1.30 kg

F) A) and B)
G) All of the above

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What is the molarity of a 17.0% by mass solution of sodium acetate,NaC2H3O2 (82.0g/mol) ,in water? The density of the solution is 1.09 g/mL.


A) 0.170 M
B) 0.207 M
C) 2.07 M
D) 2.26 M
E) 1.90 M

F) A) and E)
G) B) and E)

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Which of these compounds is a strong electrolyte?


A) H2O
B) N2
C) CH3COOH (acetic acid)
D) C2H6O (ethanol)
E) KOH

F) A) and D)
G) All of the above

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At 10°C one volume of water dissolves 3.10 volumes of chlorine gas at 1.00 atm pressure.What is the Henry's law constant of Cl2 in water? (R = 0.0821 atm • L • mol-1• K-1 )


A) 3.8 mol • L-1• atm-1
B) 0.043 mol • L-1• atm-1
C) 36 mol • L-1• atm-1
D) 3.1 mol • L-1• atm-1
E) 0.13 mol • L-1• atm-1

F) B) and C)
G) C) and D)

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What is defined as the selective passage of solvent molecules through a porous membrane from a more dilute solution to a more concentrated solution?


A) Permeability
B) Semipermeability
C) Osmotic pressure
D) Osmosis
E) Vapor pressure

F) B) and D)
G) C) and D)

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In the following diagrams,the black circles represent a solute in solution.Which diagram represents a saturated solution?


A) In the following diagrams,the black circles represent a solute in solution.Which diagram represents a saturated solution? A)    B)    C)    D)    E)
B) In the following diagrams,the black circles represent a solute in solution.Which diagram represents a saturated solution? A)    B)    C)    D)    E)
C) In the following diagrams,the black circles represent a solute in solution.Which diagram represents a saturated solution? A)    B)    C)    D)    E)
D) In the following diagrams,the black circles represent a solute in solution.Which diagram represents a saturated solution? A)    B)    C)    D)    E)
E) In the following diagrams,the black circles represent a solute in solution.Which diagram represents a saturated solution? A)    B)    C)    D)    E)

F) D) and E)
G) None of the above

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An "ideal solution" is a solution that obeys Raoult's law.

A) True
B) False

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The mole fraction of potassium nitrate in an aqueous solution is 0.0194.The solution's density is 1.0627 g/mL.What is the molarity of KNO3 in the solution?


A) 0.0194 M
B) 0.981 M
C) 1.05 M
D) 1.96 M
E) 19.4 M

F) B) and E)
G) B) and D)

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Which of the following is not a colligative property?


A) Vapor pressure lowering
B) Atmospheric pressure
C) Boiling point elevation
D) Osmotic pressure
E) Freezing point depression

F) A) and B)
G) A) and C)

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What is the osmotic pressure of a solution that contains 13.7 g of propyl alcohol (C3H7OH) dissolved in enough water to make 500.mL of solution at 27°C? (R = 0.08206 L • atm/K • mol)


A) 9.7 atm
B) 33.7 atm
C) 0.4 atm
D) 5.6 atm
E) 11.2 atm

F) A) and C)
G) B) and D)

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A solution containing 0.102 g of an unknown compound dissolved in 100.mL of water has an osmotic pressure of 28.1 mmHg at 20.°C.What is the molar mass of the compound? (R = 0.08206 L • atm/K • mol,1 atm = 760 mmHg)


A) 663 g/mol
B) 0.872 g/mol
C) 1.15 g/mol
D) 727 g/mol
E) 1.10 × 102 g/mol

F) A) and B)
G) B) and D)

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A solution that contains 55.0 g of ascorbic acid (vitamin C) in 250.g of water freezes at -2.34°C.Calculate the molar mass (in units of g/mol) of the solute. (For water,Kf = 1.86°C/m)


A) 1.26 g/mol
B) 10.9 g/mol
C) 43.6 g/mol
D) 175 g/mol
E) 277 g/mol

F) A) and B)
G) A) and E)

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Which is true regarding the solvation of a solute in a solvent?


A) Separation of solute molecules from one another is an endothermic process,and separation of solvent molecules from one another is an exothermic process.
B) Separation of solute molecules from one another is an exothermic process,and separation of solvent molecules from one another is an endothermic process.
C) Separation of solute molecules from one another,and separation of solvent molecules from one another,are both endothermic processes.
D) Separation of solute molecules from one another,and separation of solvent molecules from one another,are both exothermic processes.
E) Separation of solute molecules from one another,and separation of solvent molecules from one another,both result in a decrease in entropy.

F) A) and D)
G) A) and C)

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The solubility of nitrogen gas in water at 25°C and a nitrogen pressure of 522 mmHg is 4.7 × 10-4 mol/L.What is the value of the Henry's law constant in mol L-1• atm-1?


A) 6.8 × 10-4 mol L-1• atm-1
B) 4.7 × 10-4 mol L-1• atm-1
C) 3.2 × 10-4 mol L-1• atm-1
D) 9.0 × 10-7 mol L-1• atm-1
E) 1.5 × 103 mol L-1• atm-1

F) A) and D)
G) A) and C)

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What is the name given to a solution that contains more solute than it has the capacity to dissolve?


A) Unsaturated
B) Saturated
C) Soluted
D) Supersaturated
E) Oversaturated

F) A) and E)
G) A) and B)

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Which is defined as the maximum amount of solute that will dissolve in a given quantity of solvent at a specific temperature?


A) precipitation
B) combustion
C) solubility
D) super saturation
E) dilution

F) A) and E)
G) C) and D)

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______________ is the term used for a water loving substance.

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When 12.1 g of the sugar sucrose (a nonelectrolyte) are dissolved in exactly 800 g of water,the solution has a freezing point of -0.082°C.What is the molar mass of sucrose? (Kf of water is 1.86°C/m.)


A) 426 g/mol
B) 99.2 g/mol
C) 178 g/mol
D) 266 g/mol
E) 343 g/mol

F) A) and E)
G) A) and B)

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Which is immiscible with water?


A) Which is immiscible with water? A)    B)    C)    D)    E)
B) Which is immiscible with water? A)    B)    C)    D)    E)
C) Which is immiscible with water? A)    B)    C)    D)    E)
D) Which is immiscible with water? A)    B)    C)    D)    E)
E) Which is immiscible with water? A)    B)    C)    D)    E)

F) A) and B)
G) A) and C)

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